L. Lindoy, H. Lip, H. Louie
1977
Citations
0
Influential Citations
23
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
The changes in the 1H n.m.r. spectrum of tris(pentane-2,4-dionato)cobalt(III) in CDCl3 on incremental addition of tris(1,1,1,2,2,3,3,-heptafluoro-7,7-[2H6]dimethyl[2H3]octane-4,6-dionato)europium {Eu([2H9]fod)3} have been determined at 32°C; 1 : 1 adduct formation occurs, chemical exchange with respect to the n.m.r. time-scale being slow, and the 1 : 1 adduct has been shown by X-ray diffraction to have an unusual structure containing three bridging oxygen atoms.