K. Nakajima, Wenbin Liang, Y. Nishibayashi
Sep 22, 2016
Citations
0
Influential Citations
22
Citations
Journal
Organic letters
Abstract
Iron-catalyzed [2 + 2 + 2] cycloaddition reactions of diynes with siloxyphosphaethynes have been developed to give 2-phosphaphenol derivatives. The use of electronically neutral siloxyphosphaethynes generated in situ by the reaction of anionic phosphaethynolate with silyl triflates is key to achieving the reactions.