F. Asinger, A. Saus, J. Hartig
Jul 1, 1979
Citations
0
Influential Citations
6
Citations
Journal
Monatshefte für Chemie - Chemical Monthly
Abstract
A new synthesis of thiomorpholine by ring closure of β-chloro-β′-aminodiethylene-sulfide with potassium hydroxide is reported. Numerous reactions of thiomorpholine (1) and, especially, 2-methyl-3-ethyl-thiomorpholine (2) are described such as acylation, diacylation (3–43), reactions with sulfonic acid chlorides (44–52), isocyanates (53–61, 70–75), diisocyanates (62–66, 76–78) and isothiocyanates (67–69, 79–82), alkylation reactions (83–111) and the synthesis of thiomorpholino-dithiocarbamates (112–121).