S. Yadav, M. Gupta, Shalini Srivastav
Jul 9, 2023
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Journal
Green Chemistry & Technology Letters
Abstract
Purpose of Study: The review article explores the kinetic and mechanistic aspects of ruthenium(III) chloride catalysis in the oxidation of organic and inorganic substrates using cerium(IV) as the oxidizing agent in an aqueous acid medium. The reactions have been classified based on the type of metal ion catalyst used. The article highlights that the nature of the mechanism of catalytic oxidation of alcohols by Ce(IV) depends on the specific metal ion catalyst used and the nature of the acidic medium employed. Methodology: The article sheds light on the purpose and scope of catalytic oxidation of alcohols by Ce(IV). The oxidation of alcohols is an essential reaction in organic chemistry and has numerous applications in the synthesis of various organic compounds. The use of Ce(IV) as an oxidizing agent in the presence of a suitable catalyst can provide an efficient and selective method for the oxidation of alcohols. Principal Findings: The article discusses the role of ruthenium(III) chloride as a catalyst in the oxidation of alcohols in the presence of Ce(IV) and provides insights into the reaction mechanism. The review also highlights the importance of the nature of the acidic medium used in the reaction and its effect on the reaction kinetics and mechanism. Implications: Overall, the review article provides a comprehensive overview of the use of ruthenium(III) chloride as a catalyst in the oxidation of alcohols using Ce(IV) as an oxidizing agent in an aqueous acid medium. The insights provided in this article can be valuable for researchers working in the area of organic and inorganic chemistry.