S. Y. Men’shikov, A. Vurasko, L. Petrov
Apr 1, 1992
Citations
0
Influential Citations
3
Citations
Journal
Bulletin of the Russian Academy of Sciences, Division of chemical science
Abstract
The synthesis of heterogenized vanadyl acetylacetonate was accomplished by alkylation of a chloromethylated styrene—divinylbenzene copolymer via activation by Co(II) complexes. The effect of heterogenization on the structure of the complexes and their catalytic properties in the peroxide oxidation of anthracene was investigated by kinetic studies and EPR spectroscopy. Increased stability during oxidation of the catalytic centers of the polymer sample as compared with homogeneous vanadyl acetylacetonate was demonstrated.