Y. Efremov, R. Z. Musin, L. I. Gurarii
Oct 1, 1972
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Journal
Chemistry of Heterocyclic Compounds
Abstract
The characteristic paths of the dissociative ionization of some 1,3,2-dioxaphospholanes were established. In the case of 2-ethoxy-1,3,2-dioxaphospholane and its 4-methyl and 4,4,5,5-tetramethyl derivatives, an ethylene molecule is formed from the ethoxy group of the molecular ion, while the formation of an aldehyde (ketone) molecule is due to cleavage of the C-C and P-O bonds in the ring.