M. Pfeffer, E. Wehman, G. Koten
Feb 26, 1985
Citations
0
Influential Citations
22
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The reaction of cis or trans di(μ-chloro)bis{[2-(dimethylamino)phenyl]methyl}dipalladium with silver acetate affords the corresponding trans dimeric compound with two acetato bridges between the palladium atoms. The molecule is non-rigid in solution. A closer investigation of the product obtained previously from the reaction of the toluidine ligand (dmatH) with palladium acetate in acetic acid, shows that it is a trinuclear species of general formula Pd 3 (dmat) 2 (μ 2 -O 2 CCH 3 ) 4 , similar to species observed in palladation of olefins by palladium acetate.