C. J. Hinshaw, Gang. Peng, Raghuvir Singh
Dec 1, 1989
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Journal
Inorganic Chemistry
Abstract
As models for the molybdenum (VI/V) centers of the molybdenum hydroxylases and related enzymes, 15 new Mo(VI)-dioxo complexes (MoO 2 L) with tetradentate ligands have been synthesized and characterized. The effects of coordinating groups (N 2 S 2 , N 2 OS, and N 2 O 2 ), chelate ring size, ligand geometry and steric bulk have been investigated. X-ray crystal structures have been obtained for seven of the complexes