Paper
Novel coordination polymers and structural systematics in the hydrothermal M,M' trans-3(-3-pyridyl)acrylic acid system.
Published Aug 1, 2005 · Noel S. Gunning, C. Cahill
Dalton transactions
Q1 SJR score
36
Citations
0
Influential Citations
Abstract
The bifunctional ligand trans-3-(3-pyridyl)acrylic acid has been utilized to promote the formation of a novel hetero-metallic [Cu3(C8H6NO2)6Nd2(NO3)6] (1) and two homometallic: [Nd(C8H6NO2)3H2O] (2) and [Cu(C8H6NO2)2] x H2O (3) metal organic framework (MOF) materials. The philosophy here is that a mixture of hard (Nd3+) and softer metal cations will show preference for the carboxylic and pyridyl functional groups, respectively. As such, a 3-D topology 1 has emerged as a stable, heterometallic structure. Efforts to explore structural systematics in this system have led to the synthesis of homometallic end members and hence the formation of a 2-D coordination polymer 2, and a 1-D coordination polymer 3. Presented is an analysis of the effect of a second metal centre on coordination environment, overall structure formation, thermal and luminescence properties.
Study Snapshot
The hydrothermal M,M' trans-3(-3-pyridyl)acrylic acid system promotes the formation of novel hetero-metallic and homometallic metal organic framework materials, with potential applications in thermoelectric, photocatalytic, and luminescence applications.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
Sign up to use Study Snapshot
Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.
Full text analysis coming soon...
References
Syntheses, crystal structures and anion-exchange properties of copper(II) and cadmium(II) complexes containing a novel tripodal ligand
Copper(II) and cadmium(II) complexes containing a novel tripodal ligand show diverse structures and anion-exchange properties, with potential applications in catalysis and electrocatalysis.
2004·39citations·Wei Zhao et al.·New Journal of Chemistry
New Journal of Chemistry
Crystal-to-crystal transformations of a microporous metal-organic laminated framework triggered by guest exchange, dehydration and readsorption.
The microporous metal-organic laminated framework (1xH(2)O) can undergo crystal-to-crystal transformations by guest exchange, dehydration, and readsorption, resulting in different crystal structures with different properties.
2004·123citations·Ming‐Hua Zeng et al.·Dalton transactions
Dalton transactions
Guest sorption and desorption in the metal-organic framework [Co(INA)(2)] (INA=isonicotinate)--evidence of intermediate phases during desorption.
The metal-organic framework [Co(INA)(2)]x0.5EtOH can reversibly absorb and desorb ethanol guests, with intermediate phases forming during desolvation.
2004·57citations·Q. Wei et al.·Dalton transactions
Dalton transactions
Hydrogen sorption in functionalized metal-organic frameworks.
Hydrogen sorption in metal-organic frameworks depends on the nature of the link, with 4.2 to 9.3 molecules of H2 per formula unit at 1 atm, showing a trend in hydrogen uptake with the number of rings in the organic moiety.
2004·1092citations·J. Rowsell et al.·Journal of the American Chemical Society
Journal of the American Chemical Society
Design of new materials for methane storage.
New metal-organic materials (IRMOFs and molecular squares) show potential for efficient methane storage, potentially surpassing current experimental results by up to 36%.
2004·612citations·Tina Düren et al.·Langmuir : the ACS journal of surfaces and colloids
Langmuir : the ACS journal of surfaces and colloids
Exceptionally stable, hollow tubular metal-organic architectures: synthesis, characterization, and solid-state transformation study.
This study successfully synthesized a new three-dimensional metal-organic framework, [ZnF(AmTAZ)], with hollow nanotubular channels, maintaining its integrity to 350 degrees C and allowing for the preparation of one-dimensional crystalline nanomaterials.
2004·329citations·C. Su et al.·Journal of the American Chemical Society
Journal of the American Chemical Society
Coordination polymers assembled from angular dipyridyl ligands and CuII, CdII, CoII salts: crystal structures and properties.
New metal-organic coordination networks have been developed using 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (L1) and Cu(II), Cd(II), and Co(II) salts, resulting in diverse structures and properties.
2004·126citations·Zheng Huang et al.·Inorganic chemistry
Inorganic chemistry
A route to high surface area, porosity and inclusion of large molecules in crystals
MOF-177, a metal-organic framework with the highest surface area reported to date, combines exceptional surface area with extra-large pores capable of binding polycyclic organic guest molecules, offering potential for catalysis, separation, and gas storage applications.
2004·2352citations·H. Chae et al.·Nature
Nature
Three olefin copper(I) dimeric complexes with 2-, 3-, and 4-pyridylacrylic acid and their electrochemical properties.
Three novel highly stable 3-D copper(I)-olefin dimers were successfully synthesized by UV irradiation of 2-, 3-, and 4-pyridylacrylic acid, with H-bonds playing a key role in their stability and electrochemical properties.
2004·16citations·Yonghua Li et al.·Inorganic chemistry
Inorganic chemistry
Citations
Luminescent metal-organic frameworks
Luminescent metal-organic frameworks (MOFs) show a wide range of luminescent behaviors due to various linker arrangements and their potential use as chemical sensors.
2021·2citations·Sulagna Biswas et al.·International Journal of Experimental Research and Review
International Journal of Experimental Research and Review
Syntheses, structures and properties of a series of heterometallic-organic frameworks based on pyridinedicarboxylic acids
Six novel heterometallic-organic frameworks (HMOFs) have been synthesized using alkaline earth/rare earth/transition metal ions and pyridinedicarboxylic acids, with most having three-dimensional frameworks and some showing magnetic and luminescent properties.
2020·56citations·Zhongxin Ma et al.·Journal of Solid State Chemistry
Journal of Solid State Chemistry
Robust 2D Coordination Networks from a Two-Step Assembly Process with Predesigned Silver Cyclic Dimers and Hexamethylenetetramine
Two-step self-assembly methodology enables robust 2D coordination networks with egg-crate structure and space group R3m, offering potential applications in biosensors and drug delivery systems.
2015·17citations·Gema Durá et al.·Crystal Growth & Design
Crystal Growth & Design
Effect of CH3OH on the luminescent properties of the [Zn(sfdb)(bpy)(H2O)]n · 0.5nCH3OH metal–organic framework
CH3OH solvent changes the luminescence properties of the [Zn(sfdb)(bpy)(H2O)]n 0.5nCH3OH metal-organic framework, offering potential for diverse luminescent MOF designs.
2015·4citations·Xuedan Song et al.·Chemical Physics
Chemical Physics
Uranyl Ion Complexes with trans-3-(3-Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework
Trans-3-(3-pyridyl)acrylic acid can create heterometallic complexes with uranyl cations, resulting in a tetranuclear secondary building unit and a 3D assembly.
2014·19citations·P. Thuéry et al.·European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry
Effect of Polycarboxylate Coligands from Linear to V-shaped CuII Coordination Polymers Based on a Rigid Tripodal Ligand†
Copper(II) coordination polymers synthesized with linear and V-shaped polycarboxylate coligands show diverse structures and properties, with compound 2 showing a hydrogen-bonded three-dimensional supramolecular structure and compound 3 featuring a rare twofold interpenetrating binodal topological network
2014·3citations·Hao Wang et al.·Zeitschrift für anorganische und allgemeine Chemie
Zeitschrift für anorganische und allgemeine Chemie
Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties.
Tripodal carboxylate ligands can create novel coordination networks with strong antiferromagnetic interactions between cobalt ions, resulting in complex structures and magnetic properties.
2013·23citations·Xue‐Zhi Song et al.·Dalton transactions
Dalton transactions