D. Meinhard, F. Hollmann, W. Huhn
Oct 14, 2004
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0
Influential Citations
12
Citations
Journal
Organometallics
Abstract
A synthetic route for the preparation of 1,3-bis[diphenylphosphino]propane-1η 2 ,5η 1 -6-ethoxy-exo-5,6-dihydrodicyclopentadienylpalladium(II) hexafluoroantimonate (3a) and the tetrafluoroborate derivative (3b) is described. 3a was characterized by single-crystal X-ray structure analysis. Both species are active for the CO/ α-olefin copolymerization reaction without any additional activator or cocatalyst. The copolymerization experiments performed with this single-component catalyst (SCC) produced CO/α-olefin copolymers with similar properties compared to those resulting from the well-known di-acetonitrile-1,3-[bis(diphenylphosphino)propane-Pd(II)-bis(tetrafluoroborate) complex activated with methanol. An increase of activity and molecular weight has been achieved through polymerization in liquid propene.