Novel synthesis of hydroxyvinylethyl xylan using 4-vinyl-1,3-dioxolan-2-one

doi:10.1016/J.TETLET.2016.08.009

Paper

Novel synthesis of hydroxyvinylethyl xylan using 4-vinyl-1,3-dioxolan-2-one

Published Sep 14, 2016 · Youssef Akil, R. Lehnen, B. Saake

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Abstract

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Study Snapshot

This study presents a novel synthesis for incorporating vinyl groups into bio-polymer xylan, increasing its reactivity for radical induced reactions.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Novel synthesis of hydroxyvinylethyl xylan using 4-vinyl-1,3-dioxolan-2-one

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References

Citations

Five-Membered Cyclic Carbonates: Versatility for Applications in Organic Synthesis, Pharmaceutical, and Materials Sciences

Five-membered cyclic carbonates are versatile building blocks for organic synthesis, pharmaceutical, and materials sciences, with applications in chemical transformations and biomolecules.

Molecular modification, structural characterization, and biological activity of xylans.

Molecular modification methods have developed to enhance the biological activity of xylans, leading to the development of various xylan derivatives with specific biological activities.

Quantitative investigations of xylose and arabinose substituents in hydroxypropylated and hydroxyvinylethylated arabinoxylans.

The cyclic carbonates propylene carbonate and 4vinyl-1,3-dioxolan-2-one preferably react with arabinose, resulting in higher conversion rates and reactivity of the newly introduced side chains.

Comparison of different cyclic organic carbonates in the oxyalkylation of various types of lignin

Oxidation with ethylene, propylene, butylene, and glycerol carbonate effectively synthesizes biobased polyols from various lignins, with higher substitution degrees achieved using these cyclic organic carbonates.

Cyclic Carbonates as Safe and Versatile Etherifying Reagents for the Functionalization of Lignins and Tannins

Cyclic carbonates are a safe and versatile etherifying reagent for functionalizing lignins and tannins, offering a safe alternative to organohalides or epoxides for introducing functional groups of interest.