Asami Yamamoto, Michio. Kobayashi
Jun 1, 1966
Citations
0
Influential Citations
1
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Silver p-toluenesulfonate has been found to react with alkyl and aryl chlorosulfite to give p-toluenesulfonic esters. Mixed anhydrides of the sulfonic acid and monoalkyl or monoaryl sulfite were postulated as the intermediates. No rearrangement of the alkyl group was observed during the reaction. The reaction mechanism was studied by means of the 18O tracer technique.