A mild oxidizing reagent for alcohols and 1,2-diols: o-iodoxybenzoic acid (IBX) in DMSO

doi:10.1016/0040-4039(94)80038-3

Paper

DOI: 10.1016/0040-4039(94)80038-3

A mild oxidizing reagent for alcohols and 1,2-diols: o-iodoxybenzoic acid (IBX) in DMSO

Published Oct 24, 1994 · M. Frigerio, M. Santagostino

Tetrahedron Letters

Q3 SJR score

392

Citations

Influential Citations

Full textSemantic Scholar

Abstract

Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.

Highly Cited

Study Snapshot

O-iodoxybenzoic acid (IBX) in DMSO effectively oxidizes alcohols and 1,2-diols to aldehydes and ketones, with good to quantitative yields at room temperature.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Sign up to use Study Snapshot

Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.

Create an account

Full text analysis coming soon...

References

DOI: 10.1021/JA00067A025

Synthetic studies on quassinoids: total synthesis of (-)-chaparrinone, (-)-glaucarubolone, and (+)-glaucarubinone

This study successfully synthesized (-)-chaparrinone, (-)-glaucarubolone, and (+)-glaucarubinone using an intermolecular Diels-Alder reaction and a two-step process.

1993·71citations·P. Grieco et al.·Journal of the American Chemical Society

Journal of the American Chemical Society

DOI: 10.1016/0039-128X(93)90019-J

Tetrapropylammonium perruthenate as a mild and efficient oxidant for sensitive steroidal alcohols

Tetrapropylammonium perruthenate is a mild and efficient oxidant for sensitive steroidal alcohols, generating ketones from 3-, 11-, 15-, 17-, and 20-hydroxy steroids with good yields.

1993·15citations·C. Acosta et al.·Steroids

Steroids

DOI: 10.1002/MRC.1260271102

13C NMR study of 2‐iodoso‐ and 2‐iodoxy‐benzoic acids and their sodium salts

Iodoxybenzoic acids have a cyclic structure and are insoluble or oxidize in suitable NMR solvents, supporting their cyclic structure.

1989·26citations·A. Katritzky et al.·Magnetic Resonance in Chemistry

Magnetic Resonance in Chemistry

DOI: 10.1039/P29900001515

A structural study of 3- and 4-iodosylbenzoic acids, 3- and 4-iodylbenzoic acids, and their sodium salts

3- and 4-iodosylbenzoic acids and their sodium salts show significantly less catalytic efficiency than their 2-substituted counterparts, suggesting potential structural configurations.

1990·18citations·A. Katritzky et al.·Journal of The Chemical Society-perkin Transactions 1

Journal of The Chemical Society-perkin Transactions 1

Citations

DOI: 10.1021/acs.joc.4c00797

Protecting Group-Free Total Synthesis of (-)-Boscartin H.

The first protecting group-free total synthesis of (-)-boscartin H was achieved, resulting in a 3.6% overall yield and confirmed stereochemistry through X-ray crystallography.

2024·0citations·Hiroto Aihara et al.·The Journal of organic chemistry

The Journal of organic chemistry

DOI: 10.1021/acs.orglett.3c03286

Progress toward the Total Synthesis of Jogyamycin Using a Tandem Ichikawa/Winstein Rearrangement.

A tandem Ichikawa-Winstein rearrangement provides a novel route to synthesize jogyamycin, a potent antiprotozoal agent, using a novel transformation.

2023·1citation·Kate A. Nicastri et al.·Organic letters

Organic letters

DOI: 10.1080/1023666X.2023.2221873

Synthesis and characterization of glyceryl starch and determination of molar substitution

Glyceryl starch can be synthesized using chlorinated glycerol, with molar substitution determined, and compared to native corn starch for crystallinity, granule morphology, paste clarity, and retrogradation stability.

2023·0citations·Xue-Li Liu et al.·International Journal of Polymer Analysis and Characterization

International Journal of Polymer Analysis and Characterization

DOI: 10.1021/acs.joc.2c02398

Total Synthesis and Determination of Absolute Configuration of Cryptorigidifoliol G.

The absolute stereochemistry of Cryptorigidifoliol G is (1S,5R,7S)-cryptorigidifoliol G, which was successfully synthesized using a novel method.

2022·2citations·U. Choudhury et al.·The Journal of organic chemistry

The Journal of organic chemistry

DOI: 10.3390/nano12152542

Silver Nanoparticles Densely Grafted with Nitroxides as a Recyclable Green Catalyst in the Selective Oxidation of Alcohols

Silver nanoparticles grafted with nitroxides (N-AgNPs) effectively and efficiently perform selective oxidation of alcohols under mild conditions, offering a green, recyclable catalyst for organic synthesis.

2022·3citations·Agnieszka Krogul-Sobczak et al.·Nanomaterials

Nanomaterials

DOI: 10.1021/acs.joc.2c00877

Selectivity of Oxidizing Agents toward Axial and Equatorial Hydroxyl Groups.

Nitroxide-radical-based reagents are preferred for oxidizing equatorial hydroxyl groups, while Stevens or Dess-Martin reagents are preferred for oxidizing axial hydroxyl groups.

2022·3citations·M. Kaspar et al.·The Journal of organic chemistry

The Journal of organic chemistry

DOI: 10.1021/jacs.2c02188

Asymmetric Total Synthesis of (−)-Phaeocaulisin A

Our asymmetric total synthesis of ()-Phaeocaulisin A enables access to other guaiane-type sesquiterpenes from Curcuma phaeocaulis for medicinal chemistry and drug design.

2022·4citations·Á. Péter et al.·Journal of the American Chemical Society

Journal of the American Chemical Society