Paired electrosynthesis of cyanoacetic acid.

doi:10.1021/JO0358473

Paper

Paired electrosynthesis of cyanoacetic acid.

Published Mar 3, 2004 · B. Batanero, F. Barba, C. Sánchez-Sánchez

The Journal of organic chemistry

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45

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0

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Abstract

Cyanoacetic acid is formed by cathodic reduction of CO(2) and anodic oxidation of the tetraalkylammonium salt anion; the process is conduced in acetonitrile using a divided cell with a medium porosity glass-frit diaphragm. A mechanism for this paired electrochemical reaction is proposed.

Study Snapshot

Cyanoacetic acid is formed by cathodic reduction of CO2 and anodic oxidation of tetraalkylammonium salt anion in acetonitrile using a divided cell with a medium porosity glass-frit diaphragm.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paired electrosynthesis of cyanoacetic acid.

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References

Citations

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Electrochemical carboxylation with CO2 has shown promising potential for sustainable production of valuable chemicals, enabling the modification and upgrading of waste polymers.

Advanced Electroanalysis for Electrosynthesis

Recent advances in electroanalysis have improved the foundations of electrosynthesis, enhancing its efficiency and potential for future applications in organic, enzymatic, and microbial electrosynthesis.

A new strategy for coupling amides or nitriles with diarylketones promoted by samarium metal under the catalysis of CuI

Samarium metal promotes a novel condensation reaction of low activity -H and benzophones under mild conditions, enabling efficient conversion of diarylketone carbonyls to condensation products at room temperature.

Suppressing carboxylate nucleophilicity with inorganic salts enables selective electrocarboxylation without sacrificial anodes

Using MgBr2 as a low-cost, soluble source of Mg2+ cations, selective electrocarboxylation of various organic halides can be achieved without sacrificial anodes, promoting sustainable and practical carboxylation.

Manganese-catalyzed chlorosulfonylation of terminal alkene and alkyne via convergent paired electrolysis

Manganese-catalyzed chlorosulfonylation via convergent paired electrolysis generates high regio- and stereoselective analogs of pharmaceutical drugs and natural products.

Organic Electrosynthesis Towards Sustainability: Fundamentals and Greener Methodologies

Organic electrosynthesis methods, such as direct discharge, paired reactions, and electrocatalysis, can reduce pollution and save energy while enabling the construction of complex organic molecules.

Organic Electrochemistry: Expanding the Scope of Paired Reactions.

Paired electrochemical reactions can optimize atom and energy economy by combining various oxidation and reduction reactions, enabling efficient hydrogen gas generation and use.

Alternating current electrolysis for organic synthesis

Alternating current electrolysis offers a more environmentally friendly approach for organic synthesis due to its unique reactivity and reactivity.