J. Fawcett, R. Kemmitt, D. Russell
Jan 25, 1995
Citations
0
Influential Citations
32
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Tris(dibenzylideneacetone)dipalladium and bis(dibenzylideneacetone)platinum react with N, N-bis(dicyclohexylphosphinomethyl)methylamine, (Cy2PCH2)2NMe (Cy = cyclohexyl), and with N, N-bis(diphenylphosphinomethyl)methylamine, (Ph2PCH2)2NMe (Ph = phenyl), to give the complexes [M(dba){(R2PCH2)2NMe}] (M Pd or Pt, dba = dibenzylideneac ), R Cy or Ph. Thezerovalent platinum complex [Pt(PPh3){(Cy2PCH2)2NMe}] can be obtained by hydrazine hydrate reduction a mixture of [PtCl2Cy2PCH2)2NMe] and triphenylphosphine or one of cis-[PtCl2(PPh3)2] and (Cy2PCH2)2NMe. The crystal structure of [Pd(dba){(Cy2PCH2)2NMe}] has been determined and some reactions of the complexes are reported.