M. V. Tesakova, A. Noskov, M. I. Bazanov
2011
Citations
0
Influential Citations
14
Citations
Journal
Russian Journal of Physical Chemistry A
Abstract
Electrochemical and electrocatalytic properties of tetrakis(4-methoxyphenyl)porphyrin, tetrakis(4-methoxyphenyl)porphyrinatocobalt(II), and (tetrakis(4-methoxyphenyl)porphyrinato)chlorocobalt(III) are studied using the method of cyclic voltammetry. The redox-potentials of the electrode processes, the potentials of the half-wave and stationary rate constants for electroreduction of molecular oxygen are determined from an analysis of the voltammetric curves. The cobalt complex is found to be characterized by higher electrocatalytic activity than other analyzed compounds.