J. Phillips, D. T. Rosevear, F. Stone
Dec 1, 1964
Citations
0
Influential Citations
24
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Several new complexes in which pentafluorophenyl groups are σ-bonded to nickel have been prepared by treating bis(tertiaryphosphine)nickel dihalides, or bipyridylnickel dichloride, with pentafluorophenylmagnesium bromide and pentafluorophenyl-lithium. The synthesis of [1,2-bis(diphenylphosphino)ethane]bis(pentafluorophenyl)-cobalt is also reported. Bis(triethylphosphine)pentafluorophenylnickel chloride can be converted to [(C 2 H 5 ) 3 P] 2 Ni(C 6 F 5 )I and [(C 2 H 5 ) 3 P] 2 Ni(C 6 F 5 )SCN by metathetical reactions.