M. Okamoto, Takuya Asano, E. Suzuki
Nov 15, 2001
Citations
0
Influential Citations
9
Citations
Journal
Organometallics
Abstract
Phenyltrichlorogermane was synthesized with high selectivity, 96%, from elemental germanium, tetrachlorogermane, and chlorobenzene using no catalyst, almost all germanium and tetrachlorogermane being converted. Dichlorogermylene was formed as a reaction intermediate by the reaction of germanium with tetrachlorogermane and inserted into the C−Cl bond of chlorobenzene to yield phenyltrichlorogermane.