Seung-Ki Park, D. Baek
Jul 26, 2002
Citations
0
Influential Citations
10
Citations
Journal
Journal of Photochemistry and Photobiology A-chemistry
Abstract
Photolysis of 1-o-acetylaminophenyl-2-(pentamethyldisilanyl)ethyne 2a in benzene provides a novel intramolecular cycloaddition product 4 via 1-sila-1,2-propadiene intermediate 3. Photolysis of 1-o-amino-, allylamino-, or methoxycarbonylmethylaminophenyl-2-(pentamethyldisilanyl)ethynes 2b, 2c, or 2d in benzene only provides the reduction product 8.