M. Chaudhuri, B. Das
1985
Citations
0
Influential Citations
8
Citations
Journal
Polyhedron
Abstract
Abstract Potassium trifluoroperoxotitanate(IV) trihydrate, K[Ti(O 2 )F 3 ] · 3H 2 O, with the peroxide (O 2 2− ) being bonded to the Ti(IV) centre in a triangular bidentate manner (C 2ν ) as evidenced from the IR and laser Raman spectroscopic studies, has been synthesised from the reaction of a solution of TiO 2 in 40% HF with an excess of 30% H 2 O 2 and KOH, followed by the addition of aqueous HF to adjust the pH of the reaction solution between 8 and 9.