N. Ishikawa, T. Yokozawa
Mar 1, 1983
Citations
0
Influential Citations
25
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The preparative method for dimethyl (trifluoromethyl)malonate (4) from the adduct of perfluoro-2-methylpropene with methanol was improved, and several reactions of this base-sensitive substance were investigated. Alkylation of 4 was achieved by using CsF as a condensing agent, and the Michael addition on vinyl ketones proceeded in triethylamine–pyridine medium.