H. C. Clark, A. B. Goel, R. G. Goel
Aug 29, 1978
Citations
0
Influential Citations
9
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Bis(tri-t-butylphosphine)platinum(II) hydrides, trans-HPtX(P-t-Bu3)2 (where X Cl, Br, I and CF3CO2) and trans-H2Pt(P-t-Bu3)2, have been prepared and characterized. These hydrides, unlike platinum(II) hydrides containing less bulky phosphines, undergo facile intramolecular metalation to form the internally metalated complexes [t-Bu2PC(CH3)2CH2 ] PtX(P-t-Bu3) and [{t-Bu2PC(CH3)2CH2}PtH]2, respectively.