Tamio Hayashi, M. Konishi, T. Hioki
Nov 1, 1981
Citations
0
Influential Citations
17
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
A pair of diastereoisomeric phosphines, (R)-N,N-dimethyl-1-[2-(diphenylphosphino) ferrocenyl]-2-propanamines, have been prepared and used as ligands for nickel-catalyzed asymmetric cross-coupling of 1-phenylethylmagnesium chloride with vinyl bromide to give 3-phenyl-1-butene of 14–15% enantiomeric excess.