The preparation and some reactions of chloro(η4-cycloocta-1,5-diene)(η5-cyclopentadienyl)ruthenium(II): A versatile, new synthetic precursor for cyclopentadienylruthenium(II) chemistry

doi:10.1016/0022-328X(85)87202-8

Paper

The preparation and some reactions of chloro(η4-cycloocta-1,5-diene)(η5-cyclopentadienyl)ruthenium(II): A versatile, new synthetic precursor for cyclopentadienylruthenium(II) chemistry

Published Mar 12, 1985 · M. O. Albers, Hester Oosthuizen, D. Robinson

Journal of Organometallic Chemistry

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Abstract

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Chloro(4-cycloocta-1,5-diene)(5-cyclopentadienyl)ruthenium(II) is a versatile synthetic precursor for cyclopentadienylruthenium(II) chemistry, providing high yield synthetic

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

The preparation and some reactions of chloro(η4-cycloocta-1,5-diene)(η5-cyclopentadienyl)ruthenium(II): A versatile, new synthetic precursor for cyclopentadienylruthenium(II) chemistry

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References

Cyclopentadienyl-ruthenium and -osmium chemistry. XIII. Some complexes containing isonitrile ligands

Isonitrile ligands in cyclopentadienyl-ruthenium and -osmium complexes can be used to create cationic complexes with NH4PF6 and produce hydrogen isocyanide derivatives.

Citations

Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp∗, FeCl(dppe)Cp, RuCl(dppe)Cp∗, and RuCl(dppe)Cp

This paper presents updated and optimized multigram syntheses of FeCl(dppe)Cp, FeCl(dppe)Cp, RuCl(dppe)Cp, and RuCl(dppe)Cp, highlighting their versatility in organometallic laboratories.

Fulvene–Ruthenium and Cp–Ruthenium Complexes via [2 + 2 + 1] Cyclotrimerization of Phenylacetylene with [RuCl(Tp)(1,5-cod)]

Fulvene-Ruthenium and Cp-Ruthenium complexes were successfully isolated and characterized by various spectroscopy methods, providing insights into the synthesis of ruthenium-based materials.

Homoleptic 'sandwich' complexes of substituted tris(methimazolyl)borate ligands with ruthenium, rhodium and palladium.

Substituted Tm ligands show strong electron donor properties and preferentially adopt the 2-[S,S] mode when coordinated to electron-rich metal centers.

Ruthenium-based bioconjugates: Synthesis and X-ray structure of the mixed ligand sandwich compound RuCpiPr(p-(CO2H)C6H4Tp) and labelling of amino acids and the neuropeptide enkephalin

This study synthesized and characterized various ruthenium-based bioconjugates, which can be easily coupled to biomolecules like phenylalanine-methylester and neuropeptide enkephalin.

Synthesis, Crystal Structures and Redox Properties of Mixed-Sandwich Complexes of Ruthenium(II) with Cyclopentadienyl and Tris(pyrazolyl)methane Ligands

Mixed-sandwich ruthenium(II) complexes with cyclopentadienyl and tris(pyrazolyl)methane ligands show quasi-reversible oxidation processes, mainly influenced by the nature of the Cp ligands.