J. Purdon, J. Pagotto, Raynor K. Miller
1989
Citations
2
Influential Citations
84
Citations
Quality indicators
Journal
Journal of Chromatography A
Abstract
Abstract Studies of tert.-butyldimethylsilylation of several alkyl methylphosphonic, alkylphosphonic and chlorine-substituted alkylphosphonic acids by several derivatizing reagents under differing reaction conditions are reported and a simple procedure for formation of these derivatives is identified. Determination of the stabilities of representative derivatives are reported and capillary column gas chromatographic (GC) retention data for all the derivatives studied are tabulated. General sensitivities for detection and quantitation of these compounds by GC—flame photometric detection and GC—electron impact mass spectrometry in both full-scan and multiple-ion detection modes are presented.