T. Sekine, K. Inaba, T. Morimoto
Apr 1, 1988
Citations
0
Influential Citations
7
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The rate of solvent extraction of chromium(III) in aqueous perchlorate solutions into carbon tetrachloride as the tris(acetylacetonato) complex has been determined. The rate was first order with respect to the acetylacetone concentration and inverse first order with respect to the hydrogen-ion concentration. From this information, the rate-controlling reaction is concluded to be the formation of the first complex in the aqueous phase by a reaction between [Cr(OH)]2+ and HA.