Paper
Reaction between 5-Benzylidene-2,2-Dimethyl-1,3-Dioxane-4,6-Dione and Tert-butyl Isocyanide in the Presence of Ethane-1,2-diol or Catechol
Published Mar 1, 2007 · I. Yavari, H. Zare, B. Mohtat
Journal of Chemical Research
3
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0
Influential Citations
Abstract
tert-Butyl isocyanide undergoes a smooth reaction with 5-benzylidene-2,2-dimethyl-1,3-dioxane-4,6-diones (benzylidene Meldrum's acids) in the presence of ethane-1,2-diol or catechol to produce functionalised N-tert-butyl-2-(5,7-dioxo-1,4-dioxepane-6-yl)-2-aryl-ethanamides or bis-(2-hydroxyphenyl) 2-[2-(tert-butylamino)-1-aryl-2-oxoethyl]-malonates in good yields.
Tert-butyl isocyanide effectively reacts with 5-benzylidene-2,2-dimethyl-1,3-dioxane-4,6-diones to produce functionalized N-tert-butyl-2-(5,7-dioxo-1,4
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