S. Munavalli, D. Rohrbaugh, D. Rossman
Aug 10, 1999
Citations
0
Influential Citations
7
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract Based on the mass spectral fragmentation behavior of the reaction products, the free radical reaction of 1-ethynyl-1-cyclopentanol ( 1 ) with trifluoromethylsulfenyl chloride ( 2 ) has been found to furnish 13 compounds formed from addition and elimination reactions. Two compounds are noteworthy in that one does not have the side chain, while the other carries an extended `tri-ynyl' side chain. This paper presents the mechanism of formation of the various compounds and their GC-MS characterization.