Nico Santschi, P. Geissbühler, A. Togni
Mar 1, 2012
Citations
0
Influential Citations
29
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract The electrophilic trifluoromethylation of hydrogen phosphates with the reagent trifluoromethyl-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole ( 1 ) was studied by means of initial rates determined for pseudo first order setups and subsequent Taft analysis of the calculated relative rates. A positive polar sensitivity factor, indicative of a negative charge forming during the rate-determining step, was found for the whole data set.