S. Orysyk, V. Bon, O. A. Zholob
Mar 6, 2014
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Journal
Russian Journal of Coordination Chemistry
Abstract
The syntheses and spectral (IR, UV-VIS, XPS, and 1H and 13C NMR) characteristics of the rhodium(III), palladium(II), and platinum(II) complexes with 2-(2-hydroxybenzoyl)-N-methylhydrazinecarbothioamide (HBMHCTA) are described. The coordination of HBMHCTA to the central metal ion and its intraligand rearrangement in the complex formation of rhodium(III) ions are studied. The structure of the mixed-ligand complex [Pd(H2L)PPh3] is determined by X-ray diffraction analysis.