Jing-Xing Gao, and Takao Ikariya, R. Noyori
Feb 20, 1996
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Influential Citations
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Quality indicators
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Organometallics
Abstract
The trans-RuIICl2 complexes with structurally similar N,N‘-bis[o-(diphenylphosphino)benzylidene]cyclohexane-1,2-diamine and N,N‘-bis[o-(diphenylphosphino)benzyl]cyclohexane-1,2-diamine ligands have been synthesized, and their molecular structures have been determined. The C2-symmetric diphosphine/diamine-based Ru complex acts as an excellent catalyst precursor in asymmetric transfer hydrogenation of acetophenone in a 0.1 M 2-propanol solution, leading to 2-phenylethanol in 97% ee and in 93% yield after 7 h at 45 °C. This transfer hydrogenation is characterized by low reversibility under these conditions.