A. Alberti, M. Benaglia, A. Hudson
Sep 1, 2001
Citations
0
Influential Citations
4
Citations
Journal
Research on Chemical Intermediates
Abstract
Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate, ethyl (diethoxyphosphoryl)thiolformate, and ethyl (diethoxythiophosphoryl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters; even the former compounds, however, exhibited a remarkably lower reactivity than similarly substituted dithioesters.