Li Wu, B. Schwederski, D. W. Margerum
Sep 1, 1990
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0
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33
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Journal
Inorganic Chemistry
Abstract
The stepwise hydrolysis of tetrachloroplatinate(II) in basic solution is investigated by 195 Pt NMR spectroscopy. Four sequential reactions are observed when 0.05 M PtCl 4 2− is reacted with 1.0 M NaOH. The VV-vis spectrum of each Pt(II) species is resolved from repetitive scans on the basis of the NMR-determined rate constants