S. Troyanov, O. Gorbenko
1997
Citations
0
Influential Citations
14
Citations
Journal
Polyhedron
Abstract
Abstract The X-ray crystal structure of titanium(IV) oxo-bis-2,2,6,6-tetramethylheptan-3,5-dionate, pentane (1: 1) adduct has been determined. The tetrameric molecule of [TiO(thd)2]4 contains a nearly planar (Ti-O)4 ring with two Ti atoms on a twofold axis. Compared with the dimeric titanium oxo-bis-(acetylacetonate), another type of Ti06 octahedral connection takes place, namely through vertices instead of edges.