Paper
Fluoroaliphatic sulfones: a new class of delayed-action insecticides for control of Solenopsis invicta (Hymenoptera: Formicidae).
Published Dec 1, 1985 · R. K. Meer, C. S. Lofgren, David F. Williams
Journal of economic entomology
29
Citations
2
Influential Citations
Abstract
Extensive laboratory testing of fluoroaliphatic sulfones (RfSO2R) showed that, in particular, sulfonamide (RfSO2NR1R2) analogs have potential as delayed-action toxicants for control of the red imported fire ant, Solenopsis invicta Buren. Delayed activity was observed when R1 and R2 = H or alkyl with one exception (R1 = H, R2 = t-butyl). Dependent on the double-bond position, unsaturated hydrocarbon substituents gave either fast kill or delayed activity. Monoalcohol substituents showed delayed activity, but diols were inactive. Polyether substituents, either hydrogen or methyl end-capped, showed similar delayed activity. The C8F17 fluorocarbon radical yielded the best activity. Both the fluorocarbon and sulfone groups were essential to the activity of this class of compounds.
Fluoroaliphatic sulfones show potential as delayed-action insecticides for controlling red imported fire ants, with the C8F17 fluorocarbon radical yielding the best activity.
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