N. Yoshino, Yasushi Yamamoto, K. Hamano
Jun 1, 1993
Citations
0
Influential Citations
39
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Four silane coupling agents, (1H,1H,2H,2H-polyfluoroalkyl)trimethoxysilanes ((1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane, C10F21C2H4Si(OCH3)3, (1H,1H,2H,2H-heptadecafluorodecyl)trimethoxysilane, C8F17C2H4Si(OCH3)3, (1H,1H,2H,2H-tridecafluorooctyl)trimethoxysilane, C6F13C2H4Si(OCH3)3, and (1H,1H,2H,2H-nonafluorohexyl)trimethoxysilane, C4F9C2H4Si(OCH3)3), were prepared by the hydrosilylation of trichlorosilane with the corresponding 1H,1H,2H-polyfluoro-1-alkene in the presence of hydrogen hexachloroplatinate(IV), followed by reaction with sodium methoxide. The surface modification of glass plate was attempted using these products. From measurements of the contact angles θ (°) of water and oleic acid against a modified glass plate surface, the coupling agents were found to have high modification ability. The modification produced a glass surface with high oxidation resistance.