E. E. Mikhlina, V. Vorob'eva, K. F. Turchin
1968
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Journal
Chemistry of Heterocyclic Compounds
Abstract
A series of 3-alkyl(aryl)-3-aminoquinuclidines was synthesized by means of the interaction between 3-alkyl(aryl)-3-oxyquinuclidines and acetonitrile in the presence of concentrated sulfuric acid with subsequent hydrolysis of the 3-alkyl(aryl)-3-acetaminoquinuclidines. It was shown that in addition to acetamino derivatives 3-alkyl-Δ2-dehydroquinuclidines and 3-alkylidenequinuclidines are formed, the structure of which was established by the method of NMR.