Nasir-ud-din, D. A. Jeanloz, R. Jeanloz
Dec 1, 1974
Citations
0
Influential Citations
4
Citations
Journal
Carbohydrate research
Abstract
Abstract The 6-mono- ( 6 ) and 4,6- ( 16 ) and 3,6-di-methyl ( 25 ) ethers of methyl 2-acetamido-2-deoxy-α- D -mannopyranoside have been synthesized from 6- O -trityl, 4,6- O -benzylidene, and 3- O -methyl derivatives, respectively, by way of O -benzoyl and of O -allyl derivatives. The yields were respectively 37 and 43% for 6 , 34 and 50% for 16 , and 14 and 25% for 25 . These ethers are used as standard compounds for the structure elucidation, by methylation, of polymers containing 2-amino-2-deoxy- D -mannose.