Yongxing Tang, Hongwei Yang, Jianhua Shen
Nov 12, 2012
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0
Influential Citations
42
Citations
Journal
New Journal of Chemistry
Abstract
A high-nitrogen compound (N10 structure), 1,1′-azobis(5-methyltetrazole) which is relatively stable, was obtained by azo coupling reactions with three different oxidants such as trichloroisocyanuric acid (TCICA), sodium dichloroisocyanurate (SDIC) and tert-butyl hypochlorite (t-BuOCl). In particular, TCICA has been used for the first time to oxidize N–NH2 to the N–NN–N linkage. The structural elucidation of the title compound was made by spectral and X-ray crystallographic analyses. The new N10 linkage containing compound exhibits both relative thermal stability and physical stability.