Gang-hong Pan, X. Yin, Wenliang Xu
Dec 12, 2014
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Journal
Molecular Crystals and Liquid Crystals
Abstract
Two Zn(II)-containing complexes based on fluconazole, {[Zn(HFlu)2(IPA)]·9H2O}n (1), {[Zn(HFlu)2(OH-BDC)]·8H2O}n (2) (HFlu = fluconazole; 2-(2,4-difluoro- phenyl)-1,3-bis(1,2,4-triazol-1-yl)-propan-2-ol; H2IPA = isophthalic acid; OH-H2BDC = 5-hydroxyisophthalic acid) have been synthesized and structurally characterized. Complex 1 and 2 are both a one-dimensional (1D) tubular structure with the distorted dinuclear zinc rectangular-shaped cavity, and large free water molecules involved in strong O‒H···O and O‒H···N hydrogen bonds are accommodated in the 1D tubular structure. The thermal stabilities and photoluminescent properties of the coordination polymers have also been investigated.