Satyamaheshwar Peddibhotla, J. Tepe
Sep 21, 2004
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64
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Journal
Journal of the American Chemical Society
Abstract
We report herein a silver(I)-catalyzed exo-selective synthesis of highly substituted Delta1-pyrroline scaffolds from amino acid-derived münchnones. Silver acetate successfully catalyzed the cycloaddition reaction of azlactones with alkenes, generating Delta1-pyrrolines in very good yields without isomerization to the Delta2-pyrrolines or decarboxylation.