Synthesis and oxidation of 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,4-cyclohexadiene

doi:10.1016/S0022-328X(00)92840-7

Paper

DOI: 10.1016/S0022-328X(00)92840-7

Synthesis and oxidation of 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,4-cyclohexadiene

Published 1973 · Y. Nakadaira, H. Sakurai

Journal of Organometallic Chemistry

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Abstract

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The synthesis of 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,4-cyclohexadiene from 1,4-dilithiotetrapheynylbutadiene and 1,2-dichlorot

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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References

Citations

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DFT investigation of the ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls: a crucial intramolecular Si–Si bond activation

The ring contraction reaction of (4-1,2-disilacyclohexadiene)iron tricarbonyls is primarily driven by the intramolecular activation of the Si–Si bond using iron, leading to the formation of intermediates and the six-membered ring product 8.

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Comparative studies of the geometric and electronic properties of 1,1-disubstituted-2,3,4,5-tetraphenylsiloles and 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,5-cyclohexadiene

The addition of a silicon atom significantly alters the geometric and electronic properties of 1,1-disubstituted-2,3,4,5-tetraphenylsiloles and 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila

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Domino Oxidation of Ladder Oligosilanes:Formation of Novel Ladder Frameworks Containing Oligosiloxane and Oligosilane Chains

Domino oxidation of ladder oligosilanes leads to novel ladder frameworks with intense UV absorption bands, offering potential applications in UV-sensitive materials.

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Photoinduced Electron Transfer from Tetraphenyl-Substituted 1,2-Digermacyclohexa-3,5-dienes and Related Compounds to C60

Photoinduced electron transfer from 1,2-digermacyclohexa-3,5-dienes to C60 leads to the formation of cyclic oxadigerma compounds, with the formation of 1-germacyclopenta-2,4-dienes and 1-oxa-2,7-

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Dehydrocondensation of trialkylsilanes with acetylene and substituted acetylenes produces 90% yield of trialkyl(organylethynyl)silanes in hexane or benzene, with products including bis(trie

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PHOTOLYSIS AND THERMOLYSIS OF 1,2,3-TRISILACYCLOPENTENE. REGIOSPECIFIC AND NON-REGIOSPECIFIC SILYLENE EXTRUSION

Photolysis of 1,2,3-trisilacyclopent-4-ene generates silylene, with the central silicon being ejected as silylene regiospecifically on thermolysis.

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Chemistry of organosilicon compounds 118. Novel ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls

Novel ring contraction reaction occurs in (η4-1,2-disilacyclohexadiene)iron tricarbonyls, leading to (η4-1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene)iron tricarbonyl upon thermolysis at 160°C.

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Synthese de cyclodisilanes fonctionnels. Essais d'obtention de disilanes optiquement actifs

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