M. Westerhausen
May 7, 1991
Citations
0
Influential Citations
229
Citations
Quality indicators
Journal
ChemInform
Abstract
Alkaline-earth-metal bis[bis(trimethylsilyl)amides] of magnesium, calcium, strontium, and barium have been isolated in high yield from bis[bis(trimethylsilyl)amido] tin (II) by utilizing the transmetalation reaction in common organic solvents. When this reaction is performed in 1,2-dimethoxyethane, an ether adduct with two DME molecules is formed for each metal. The alkaline-earth-metal diamides without complexating reagents appear to be dimeric in benzene and toluene