Vassilios Meladinis, R. Herrmann, O. Steigelmann
Nov 1, 1989
Citations
0
Influential Citations
6
Citations
Journal
Zeitschrift für Naturforschung B
Abstract
Oxidation of (3-oxo-camphorsulfonyl)imine (1) by magnesium monoperoxyphthalate does not lead to the oxaziridine obtained with 3-chloro-perbenzoic acid, but to a new chiral oxaziridine containing an additional oxygen atom (Baeyer-Villiger type oxidation). The structure of the product is established by X-ray crystallography, and reaction pathways for the oxidation of 1 by peracids are discussed.