J. Pinkas, R. Gyepes, P. Štěpnička
Oct 1, 2004
Citations
0
Influential Citations
4
Citations
Journal
Inorganic Chemistry Communications
Abstract
Abstract Bis{η5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{η5-C5Me4(SiMe2NMe2)}2] (1), reacts with sulfane under cleavage of both Si–N and Ti–Cl bonds to give sulfido-tethered titanocene compound bis{η5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-κS)cyclopentadienyl}titanium(IV), [Ti{η5-C5Me4(SiMe2S- κS)}2] (4), and dimethylamine hydrochloride as the byproduct. The crystal structure of compound 4 has been determined by single-crystal X-ray diffraction.