J. Bakos, I. Tóth, G. Szalontai
Jul 18, 1989
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Influential Citations
2
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Journal
Journal of Organometallic Chemistry
Abstract
Abstract The [Rh(( S , S )-BDPP) 2 ] + ( 1 ) cation, where BDPP (−)-(2 S ,4 S )-2,4-bix(diphenylphosphino)pentane, has been synthesized and fully characterized by spectroscopy and by an X-ray diffraction study of the solvated chloride salt. The coordination about Rh is slightly distorted square planar and the six-membered chelate rings adopt skew conformation. Oxidative addition of HCl to 1 yields the trans -chlorohydrido derivative ( 2 ). In the octahedral complex the six-membered chelate rings have the chair conformation, as evidenced by 1 H, 13 C and 31 P NMR spectroscopy.