Taek-Jin Kang, Won-Yeob Kim, Yeokwon Yoon
Oct 20, 2011
Citations
0
Influential Citations
30
Citations
Journal
Journal of the American Chemical Society
Abstract
A tandem reaction strategy for forming triquinanes from linear allenyl diazo compounds through an intramolecular 1,3-dipolar cycloaddition reaction of an allenyl diazo group that generates a trimethylenemethane (TMM) diyl followed by an intramolecular [2 + 3] TMM diyl cycloaddition reaction has been developed. The new tandem cycloaddition reaction is readily applicable to the synthesis of complex molecules with high versatility and efficiency.