H. Roesky, M. Scholz, M. Noltemeyer
Dec 1, 1990
Citations
0
Influential Citations
24
Citations
Journal
Chemische Berichte
Abstract
Reactions of 2,4,6-Tris(trifluoromethyl)phenols with Compounds of Main Group (Li, Na, Mg, Ca. Ba, Ge. Sn) and Transition (Ti, W, Mn, Cd) Elements The 2,4,6-tris(trifluoromethyl)phenoxides of composition RfONa · 1.5 THF (2), [Rf = 2,4,6-(CF3)3C6H2], RfOLi · 0.75 Et2O (3), (RfO)2Mg · 3 THF (4), (RfO)2Ca · 3 THF (5), (RfO)2Ba · THF (6), (RfO)2 (7), (RfO)2Me2NWWNMe2(ORf)2 (8), (RfO)2Ge · THF (9), (RfO)2Sn · THF (10), (η5-C5Me5)TiCl2ORf (11), (RfO)2Mn · 3 THF (12), and (RfO)2 · 2 THF (13) are prepared. The singlecrystal X-ray structures of 4, 8, and 12 are described.