A. Baranov, T. Sukhikh, A. Artem’ev
2022
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Журнал структурной химии
Abstract
1,2-Bis[bis(pyridin-2-ylmethyl)phosphino]ethane, R2PCH2CH2PR2 (R = 2-PyCH2), has been synthesized in 92% yield via the reaction of Cl2PCH2CH2PCl2 with 2-[(trimethylsilyl)methyl]pyridine. Treatment of this phosphine with Pd(COD)Cl2 affords chelating complex of [PdLCl2] type, wherein the Pd(II) ion displays a square-planar [Pd@Cl2P2] geometry.