C. G. Francisco, A. Herrera, Ángeles Martín
Sep 3, 2007
Citations
0
Influential Citations
28
Citations
Journal
Tetrahedron Letters
Abstract
Abstract The preparation of 2-amino- C -glycosides of the hexahydro-2 H -furo[3,2- b ]pyrrole and octahydropyrano[3,2- b ]pyrrole systems is described. A tandem 1,5-hydrogen atom transfer–radical oxidation–nucleophilic cyclisation mechanism is proposed for the intramolecular hydrogen atom transfer reaction promoted by carbamoyl and phosphoramidyl radicals employing hipervalent iodine oxidants.